LOW-FREQUENCY RAMAN-ACTIVE VIBRATION OF HEXAGONAL BORON-NITRIDE

被引:79
作者
KUZUBA, T
ERA, K
ISHII, T
SATO, T
机构
[1] National Institute for Researches in Inorganic Materials, Niihari-gun, Ibaraki, 300-31, Kurakake, Sakura-Mura
关键词
D O I
10.1016/0038-1098(78)90288-0
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Raman spectra of single crystals and powder of hexagonal boron nitride have been measured at room temperature. Two Raman lines due to phonons of 52.5 and 1366 cm-1 were observed. The 52.5 cm-1 line, observed for the first time, has been attributed to the shear-type rigid layer mode of the crystal. The force constants related with the vibrations of these modes and their anisotropy are compared with those of graphite. © 1978.
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页码:863 / 865
页数:3
相关论文
共 10 条
[1]  
Babich I. L., 1972, Theoretical and Experimental Chemistry, V8, P594, DOI 10.1007/BF00526930
[2]  
Brillson L. J., 1971, PHYSICS SEMIMETALS N, P187
[3]   NORMAL MODES IN HEXAGONAL BORON NITRIDE [J].
GEICK, R ;
PERRY, CH ;
RUPPRECH.G .
PHYSICAL REVIEW, 1966, 146 (02) :543-&
[4]  
ISHII T, UNPUBLISHED
[5]   VIBRATION SPECTRUM OF GRAPHITE AND BORON NITRIDE .2. 3-DIMENSIONAL SPECTRUM [J].
NEWELL, GF .
JOURNAL OF CHEMICAL PHYSICS, 1957, 27 (01) :240-250
[6]   VIBRATION SPECTRUM OF GRAPHITE AND BORON NITRIDE .1. 2-DIMENSIONAL SPECTRUM [J].
NEWELL, GF .
JOURNAL OF CHEMICAL PHYSICS, 1956, 24 (05) :1049-1060
[7]   LATTICE-DYNAMICS OF PYROLYTIC-GRAPHITE [J].
NICKLOW, R ;
SMITH, HG ;
WAKABAYA.N .
PHYSICAL REVIEW B, 1972, 5 (12) :4951-&
[8]   AN X-RAY STUDY OF BORON NITRIDE [J].
PEASE, RS .
ACTA CRYSTALLOGRAPHICA, 1952, 5 (03) :356-&
[9]   NMR STUDY OF BONDING IN SOME SOLID BORON COMPOUNDS [J].
SILVER, AH ;
BRAY, PJ .
JOURNAL OF CHEMICAL PHYSICS, 1960, 32 (01) :288-292
[10]   RIGID-LAYER MODES IN CHALCOGENIDE CRYSTALS [J].
ZALLEN, R ;
SLADE, M .
PHYSICAL REVIEW B, 1974, 9 (04) :1627-1637