SEMICONDUCTOR PROPERTIES OF IRON-OXIDE ELECTRODES

被引:165
作者
WILHELM, SM
YUN, KS
BALLENGER, LW
HACKERMAN, N
机构
[1] Department of Chemistry, Rice University, Houston
关键词
electrolysis; ion oxides; passivity; photocurrent;
D O I
10.1149/1.2129055
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The semiconductor electrode properties of thermally grown iron oxide and anodic oxide films on iron are compared. The bandgaps are 2.1 and 1.9 eV respectively. Donor densities and flatband potentials are reported. Measurement of the currents produced by chopped illumination (f 100 Hz) has allowed evaluation of electrode parameters and determination of reaction pathways. © 1979, The Electrochemical Society, Inc. All rights reserved.
引用
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页码:419 / 424
页数:6
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