A REGIOSELECTIVE DIELS-ALDER SYNTHESIS OF ELLIPTICINE

被引：48

作者：

DAVIS, DA ^{[1
]}

GRIBBLE, GW ^{[1
]}

机构：

[1] DARTMOUTH COLL,DEPT CHEM,HANOVER,NH 03755

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(00)88731-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The trimethylsilyl trifluoromethanesulfonate accelerated Diels-Alder reaction between 1,3-dimethyl-4-(phenylsulfonyl)-4H-furo[3,4-b]indole (3) and 5,6-dihydropyridones (10) shows high regioselectivity, yielding carbazole 11 upon hydrolytic workup. Carbazole 11b has been successfully converted to the pyridocarbazole alkaloid ellipticine (1). © 1990.

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页码：1081 / 1084

页数：4

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