ARTIFICIAL MOLECULAR ANION HOSTS - SYNTHESIS OF A CHIRAL BICYCLIC GUANIDINIUM SALT SERVING AS A FUNCTIONALIZED ANCHOR GROUP FOR OXO ANIONS

被引：35

作者：

GLEICH, A ^{[1
]}

SCHMIDTCHEN, FP ^{[1
]}

机构：

[1] TECH UNIV MUNICH,LEHRSTUHL ORGAN CHEM & BIOCHEM,LICHTENBERGSTR 4,W-8046 GARCHING,GERMANY

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 04期

关键词：

Molecular recognition / Anion host compound / Guanidmiun salt / Chiral synthesis;

D O I：

10.1002/cber.19901230442

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Artificial Molecular Anion Hosts. Synthesis of a Chiral Bicyclic Guanidinium Salt Serving as a Functionalized Anchor Group for 0x0 Anions Starting from 1‐asparagine, the synthesis of the S,S‐bis(hydroxymethyl)‐substituted bicyclic guanidinium salt 3 is described, which is obtained in 20% overall yield with a diastereomeric excess de > 98%. The guanidinium compound 3 may serve as a binding module in the enantioselective recognition of oxo anions in polytopic abiotic receptors. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：907 / 915

页数：9

共 45 条

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