EFFECT OF ELECTRODE SURFACE-AREA ON CHAOTIC ATTRACTOR DIMENSIONS

被引：34

作者：

WANG, Y

HUDSON, JL

机构：

[1] Dept. of Chemical Engineering, University of Virginia, Charlottesville, Virginia

来源：

AICHE JOURNAL | 1991年 / 37卷 / 12期

关键词：

D O I：

10.1002/aic.690371208

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

An experimental study of the dynamics of electrodissolution of iron in sulfuric acid is reported. The experiments were done under potentiostatic conditions with a rotating disk electrode as a function of two parameters, potential and electrode diameter. The dynamic behavior depends strongly on the latter parameter; with increasing electrode size we observe transitions from periodic oscillations to low-order chaos to higher-order chaos. The attractor dimension increases with increasing electrode size. In addition, for the large electrodes at more positive potentials, a secondary higher frequency oscillation also arises.

引用

页码：1833 / 1843

页数：11

共 45 条

[1] AN EXPERIMENTAL INVESTIGATION OF PERIODIC AND CHAOTIC ELECTROCHEMICAL OSCILLATIONS IN THE ANODIC-DISSOLUTION OF COPPER IN PHOSPHORIC-ACID [J].