PLATINACYCLOBUTANE COMPLEXES FROM NUCLEOPHILIC-ATTACK AT A COORDINATED ALLYL GROUP AND CATALYTIC FORMATION OF CYCLOPROPANES IN THE PRESENCE OF PLATINUM COMPLEXES

被引：25

作者：

CARFAGNA, C

GALARINI, R

MUSCO, A

SANTI, R ^{[1
]}

机构：

[1] IST G DONEGANI SPA MONTEDISON,VIA FAUSER 4,I-28100 NOVARA,ITALY

[2] UNIV URBINO,IST SCI CHIM,I-61029 URBINO,ITALY

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 12期

关键词：

D O I：

10.1021/om00058a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silylketene acetals react with allylplatinum complexes to yield platina(II)cyclobutanes 4 through nucleophilic attack at the central carbon atom of the allyl group. Cyclopropane 9 has been prepared catalytically from allyl acetate and (CH3)2C = C(OMe)(OSiMe3).

引用

页码：3956 / 3958

页数：3

共 16 条

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