STUDIES ON A SERIES OF BIS-ARYLIMIDES CONTAINING 4 PHENYLENE RINGS AND THEIR POLYMERS .3. KINETIC-ANALYSIS OF THE THERMAL POLYMERIZATIONS

被引：14

作者：

BARTON, JM ^{[1
]}

HAMERTON, I ^{[1
]}

ROSE, JB ^{[1
]}

WARNER, D ^{[1
]}

机构：

[1] UNIV SURREY,DEPT CHEM,GUILDFORD GU2 5XH,SURREY,ENGLAND

来源：

POLYMER | 1992年 / 33卷 / 17期

关键词：

BIS-MALEIMIDES; BIS-CITRACONIMIDES; DIFFERENTIAL SCANNING CALORIMETRY; THERMAL POLYMERIZATION; KINETICS; PURITY;

D O I：

10.1016/0032-3861(92)90653-E

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of aryl bis-maleimides (BMIs) and bis-citraconimides (BCIs) were characterized by d.s.c. using both temperature scans and isothermal experiments. Impurities in the BMIs tend to increase the temperature at which thermal polymerization starts, while the converse is true for BCIs. This was attributed to the presence of an itaconimide impurity in the BCIs. In particular, the thermal polymerization kinetics of the compounds were investigated. Effects of structure and monomer purity on the thermal polymerization characteristics were identified.

引用

页码：3664 / 3669

页数：6

共 17 条

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