THERMODYNAMIC PROPERTIES OF A SINGLE-CRYSTAL OF FULLERENE C-60 - A DSC STUDY

被引：56

作者：

DEBRUIJN, J

DWORKIN, A

SZWARC, H

GODARD, J

CEOLIN, R

FABRE, C

RASSAT, A

机构：

[1] UNIV PARIS 11,PHYS SOLIDES LAB,CNRS,URA 2,F-91405 ORSAY,FRANCE

[2] FAC PHARM TOURS,CHIM PHYS LAB,F-37042 TOURS,FRANCE

[3] ECOLE NORMALE SUPER,ACTIVAT MOLEC LAB,CNRS,URA 1110,F-75231 PARIS,FRANCE

来源：

EUROPHYSICS LETTERS | 1993年 / 24卷 / 07期

关键词：

D O I：

10.1209/0295-5075/24/7/008

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

A 3.89mg single crystal of fullerene C-60 was grown by sublimation and its thermodynamic properties were determined through DSC measurements. The transition temperature and enthalpy are the highest ones that were ever measured (T-tr = (261.4+/-0.5)K and Delta(tr)H = (9.0+/-0.5)kJmol(-1), respectively) and are thought to be near-standard ones. However, it is shown that mechanical grinding smears out the DSC transition peak. Constraints which develop along free (111) surfaces are assumed to be responsible for this phenomenon.

引用

页码：551 / 556

页数：6

共 25 条

[1] MORPHOLOGICAL VERSATILITY OF SOLID C-60 FULLERENE .1. SOLID-STATE STUDIES OF YELLOW PLATES GROWN FROM BENZENE SOLUTIONS [J].

AGAFONOV, V ;

CEOLIN, R ;

SIZARET, PY ;

DWORKIN, A ;

ANDRE, D ;

SZWARC, H ;

FABRE, C ;

RASSAT, A ;

STRAVER, L ;

DUGUE, J ;

TAYLOR, R ;

ZAHAB, A ;

BERNIER, P .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1992, 89 (09) :1879-1886

[2] 2 DIFFERENT FULLERENES HAVE THE SAME CYCLIC VOLTAMMETRY [J].

ALLEMAND, PM ;

KOCH, A ;

WUDL, F ;

RUBIN, Y ;

DIEDERICH, F ;

ALVAREZ, MM ;

ANZ, SJ ;

WHETTEN, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) :1050-1051

[3] INTERCALATION OF MOLECULAR-SPECIES INTO THE INTERSTITIAL SITES OF FULLERENE [J].

ASSINK, RA ;

SCHIRBER, JE ;

LOY, DA ;

MOROSIN, B ;

CARLSON, GA .

JOURNAL OF MATERIALS RESEARCH, 1992, 7 (08) :2136-2143

[4] The heat capacity and entropy, heats of transition, fusion and vaporization and the vapor pressures of cyclohexane - The vibrational frequencies of alicyclic ring systems [J].

Aston, JG ;

Szasz, GJ ;

Fink, HL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1943, 65 :1135-1143

[5] HEAT-CAPACITY MEASUREMENTS AND THERMODYNAMIC STUDIES OF THE NEW COMPOUND-C-6(0) [J].

ATAKE, T ;

TANAKA, T ;

KAWAJI, H ;

KIKUCHI, K ;

SAITO, K ;

SUZUKI, S ;

IKEMOTO, I ;

ACHIBA, Y .

PHYSICA C, 1991, 185 :427-428

[6] HEAT-CAPACITY AND ORIENTATIONAL PHASE-TRANSITION OF SOLID C-60 PREPARED WITH DIFFERENT SOLVENTS [J].

ATAKE, T ;

TANAKA, T ;

KAWAJI, H ;

KIKUCHI, K ;

SAITO, K ;

SUZUKI, S ;

ACHIBA, Y ;

IKEMOTO, I .

CHEMICAL PHYSICS LETTERS, 1992, 196 (3-4) :321-324

[7] STRUCTURAL PHASE-TRANSITIONS IN THE FULLERENE C-60 [J].

DAVID, WIF ;

IBBERSON, RM ;

DENNIS, TJS ;

HARE, JP ;

PRASSIDES, K .

EUROPHYSICS LETTERS, 1992, 18 (03) :219-225

[8]

DWORKIN A, 1991, CR ACAD SCI II, V312, P979

[9] INFLUENCE OF OXYGEN ON CRYSTALLINE FULLERENE C-60 - A DSC STUDY [J].

DWORKIN, A ;

SZWARC, H ;

CEOLIN, R .

EUROPHYSICS LETTERS, 1993, 22 (01) :35-38

[10]

DWORKIN A, 1991, CR ACAD SCI II, V313, P1017

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