A ROTATING-DISK CELL FOR RAMAN SPECTROELECTROCHEMISTRY - INVESTIGATION OF AN ELECTRODE SURFACE SPECIES AND AN ELECTROGENERATED SOLUTION SPECIES

被引：35

作者：

PEMBERTON, JE ^{[1
]}

BUCK, RP ^{[1
]}

机构：

[1] UNIV N CAROLINA,KENAN LABS CHEM,CHAPEL HILL,NC 27514

来源：

APPLIED SPECTROSCOPY | 1981年 / 35卷 / 06期

关键词：

ELECTRODES;

D O I：

10.1366/0003702814732238

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

A Raman spectroelectrochemical cell has been developed which incorporates a rotating disk design. This cell has been shown to be useful for the Raman investigation of electrode surface species (spinning electrode) and electrogenerated solution species (static electrode). It has been used to characterize the Raman spectroelectrochemical behavior of photolabile dithizone anion adsorbed at silver and copper electrode surfaces. Use of this cell for the study of electrogenerated solution species was demonstrated by the resonance Raman characterization of the tetracyanoethylene anion radical electrogenerated with a cyclic potential step. Cell construction is described and its merits discussed.

引用

页码：571 / 576

页数：6

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