SHOCK-WAVE STUDY OF THE THERMAL-DISSOCIATION OF CF3NO

被引：23

作者：

GLANZER, K

MAIER, M

TROE, J

机构：

[1] Institut für Physikalische Chemie der Universität

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 61卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)85112-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The thermal dissociation of CF3NO has been tudied in shock wave experiments between 740 and 950 K in the fall-off range of the unimolecular reaction. A bond dissociation energy for the CF3NO bond of 42 kcal mol-1 was derived from the data. This yields a heat of formation of CF3NO at ΔH0 f = -132.2 ± 3 kcal mol-1 at 0 K. © 1979.

引用

页码：175 / 178

页数：4

共 22 条

[1]

BATT L, 1973, INT J CHEM KINET, V5, P1067

[2] C-N BOND-DISSOCIATION ENERGIES IN SOME HALOGENATED C-NITROSO-COMPOUNDS AND IN DI-T-BUTYL NITROXIDE [J].