SOLUBILITY OF CARBON IN LIQUID AL AND STABILITY OF AL4C3

被引：88

作者：

QIU, C

METSELAAR, R

机构：

[1] Laboratory of Solid State Chemistry and Materials Science, Eindhoven University of Technology, 5600 MB Eindhoven

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1994年 / 216卷 / 01期

关键词：

THERMODYNAMICS; ALUMINUM; CARBON SOLUBILITY; ALUMINUM CARBIDE;

D O I：

10.1016/0925-8388(94)91042-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Using thermodynamic models the properties of the Al-C liquid phase have been evaluated from experimental information on the carbon solubility in liquid Al. After slight modification of the description of Al4C3 presented by Gluschko and Gurvitch [1], the solubility has been described very well from 950 to 2500 degrees C with a regular solution model for the liquid phase. Stability of Al4C3 was examined through thermodynamic calculations under various conditions. It has been shown that the description of Al4C3 can account very well for most thermochemical measurements in a wide temperature range.

引用

页码：55 / 60

页数：6

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