CATALYTIC PROPERTIES OF PDCU AL2O3 SYSTEM OBTAINED VIA ANCHORED METAL-COMPLEXES

被引：16

作者：

NOSOVA, LV

ZAIKOVSKII, VI

RYNDIN, YA

机构：

[1] Boreskov Institute of Catalysis, Novosibirsk

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1994年 / 53卷 / 01期

关键词：

D O I：

10.1007/BF02070122

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The TON of PdCu/Al2O3 is two orders of magnitude lower 23 in ethane hydrogenolysis and several times lower in vinylacetylene and CO hydrogenation as compared to that of a Pd/Al2O3 catalyst. Nonadditivity of the catalytic properties indicates the formation of bimetallic particles, whose thermal stability is lower than that of the monometallic one.

引用

页码：131 / 138

页数：8

共 10 条

[1]

BRANDON RW, 1968, J CHEM SOC CHEM COMM, V12, P677

[2] ROLE OF CU IN THE HYDROGENOLYSIS OF PENTANE ON CU ALLOY CATALYSTS [J].