CRYSTAL-STRUCTURE OF NA3NO4

被引：27

作者：

JANSEN, M

机构：

[1] Institut Für Anorganische Und Analytische Chemie Der Universität, Giessen, D-6300

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 09期

关键词：

D O I：

10.1002/anie.197906982

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

NO 43− is the “smallest” tetrahedral oxoanion so far, as shown by X‐ray structure analysis of painstakingly group (240 d) single crystals of Na3NO4. The NO distances (139 pm) are shorter than expected (ca. 150 pm); the shortening can only be due to polar interactions superimposed on the single bond. In this way, the bond lengths in PO 43−, SO 42−, or ClO 4− could also be explained without invoking pd‐π bonding. Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：698 / 698

页数：1

共 10 条

[1] ROLE OF 3D-ORBITALS IN PI-BONDS BETWEEN .A. SIICON, PHOSPHORUS, SULPHUR, OR CHLORINE AND .B. OXYGEN OR NITROGEN [J].

CRUICKSHANK, D .

JOURNAL OF THE CHEMICAL SOCIETY, 1961, (DEC) :5486-&

[2]

Jansen, 1976, ANGEW CHEM, V88, P410

[3] DETECTION OF AN ORTHONITRATE BY VIBRATIONAL SPECTROSCOPY-NA3NO4 [J].

JANSEN, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (08) :534-535

[4] NA3NO3 - NOT AN ORTHO-NITRITE [J].

JANSEN, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1976, 15 (06) :376-377

[5] NEW INVESTIGATIONS ON NA3NO3 [J].

JANSEN, M .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1977, 435 (NOV) :13-20

[6]

JANSEN M, 1977, ANGEW CHEM, V89, P567

[7]

JANSEN M, 1978, THESIS U GIESSEN

[8] EXISTENCE OF NS3, NS3-4, NO3-4, CO4-4 AND CS4-4 ANIONS - SEMIEMPIRICAL MOLECULAR-ORBITAL CALCULATIONS [J].

JOHNSON, DK ;

WASSON, JR .

INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1974, 10 (10) :891-894

[9]

PAULING L, 1968, NATURE CHEM BOND

[10] ON RIGID-BODY MOTION OF MOLECULES IN CRYSTALS [J].

SCHOMAKER, V ;

TRUEBLOOD, KN .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1968, B 24 :63-+

← 1 →