TERNARY INTERMETALLIC PHASES OF LITHIUM, TRANSITION-METALS OF THE 4TH GROUP AND ELEMENTS OF THE 5TH MAIN GROUP WITH STATISTICAL METAL DISTRIBUTION IN THE CATION - SUBSTRUCTURE

被引：7

作者：

ADAM, A ^{[1
]}

SCHUSTER, HU ^{[1
]}

机构：

[1] UNIV COLOGNE,INST ANORGAN CHEM,GREINSTR 6,W-5000 COLOGNE 41,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 597卷 / 06期

关键词：

INTERMETALLIC PHASES (TERNARY); LITHIUM; 4A-METALS; 5B-ELEMENTS; PREPARATION; CRYSTAL STRUCTURE; X-RAY; NEUTRON SCATTERING;

D O I：

10.1002/zaac.19915970106

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The results of X-ray investigations and neutron diffraction on new and in some cases already known [1, 2] ternary intermetallic phases of Lithium with transition metals of the 4th group (b) and those of the 5th main group (X = P, As, Sb, Bi) will be reported. They crystallize in a partly "filled" antifluorite type structure with a statistical Li/B-distribution in the tetrahedral sites. The structures are obviously stabilized by small amounts of enclosed d-elements.

引用

页码：33 / 39

页数：7

共 7 条

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[3]

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[5] A PROFILE REFINEMENT METHOD FOR NUCLEAR AND MAGNETIC STRUCTURES [J].

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[6]

SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

[7]

STEWART JM, 1972, TR192 U MAR COMP SCI

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