SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [PT2(MU-H)(MU-S)(DPPE)2]+, A DIPLATINUM CATION WITH HYDRIDO AND SULFIDO LIGANDS BRIDGING A PT-PT BOND

被引：7

作者：

CAPDEVILA, M

GONZALEZDUARTE, P ^{[1
]}

MIRA, I

SOLA, J

CLEGG, W

机构：

[1] UNIV AUTONOMA BARCELONA,DEPT QUIM,E-08193 BARCELONA,SPAIN

[2] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

POLYHEDRON | 1992年 / 11卷 / 23期

关键词：

D O I：

10.1016/S0277-5387(00)80179-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [Pt(SC5H9NMe)2(dppe)] with [PtCl2(dppe)] in organic solutions containing small amounts of phosgene as an impurity gives the cation [Pt2(mu-H)(mu-S)(dppe)2]+. The product is characterized by X-ray crystallography and the hydrido bridge by NMR spectroscopy.

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页码：3091 / 3093

页数：3

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