SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [PT2(MU-H)(MU-S)(DPPE)2]+, A DIPLATINUM CATION WITH HYDRIDO AND SULFIDO LIGANDS BRIDGING A PT-PT BOND

被引:7
作者
CAPDEVILA, M
GONZALEZDUARTE, P [1 ]
MIRA, I
SOLA, J
CLEGG, W
机构
[1] UNIV AUTONOMA BARCELONA,DEPT QUIM,E-08193 BARCELONA,SPAIN
[2] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND
关键词
D O I
10.1016/S0277-5387(00)80179-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of [Pt(SC5H9NMe)2(dppe)] with [PtCl2(dppe)] in organic solutions containing small amounts of phosgene as an impurity gives the cation [Pt2(mu-H)(mu-S)(dppe)2]+. The product is characterized by X-ray crystallography and the hydrido bridge by NMR spectroscopy.
引用
收藏
页码:3091 / 3093
页数:3
相关论文
共 18 条
[1]   1ST CHELATE COMPLEXES OF 4-MERCAPTO-1-METHYLPIPERIDINE - SYNTHESIS AND CHARACTERIZATION OF [(M(MU-SC5H9NME)X)2] (M = PDII, X = CL, BR, OR I, M = PTII, X = BR OR I) - CRYSTAL AND MOLECULAR-STRUCTURE OF [(PT(MU-SC5H9NME)BR)2] [J].
AYLLON, JA ;
GONZALEZDUARTE, P ;
MIRAVITLLES, C ;
MOLINS, E .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (06) :1793-1797
[2]   1,1' BIS(DIPHENYLPHOSPHINO)FERROCENE COMPLEXES OF PLATINUM(II) AND PLATINUM(I) - CRYSTAL AND MOLECULAR-STRUCTURE OF [(FE(ETA-5-C5H4PPH2)PT(MU-H)(MU-CO)PT(FE(ETA-5-C5H4PPH2)2)][BF4]-0.5H2O [J].
BANDINI, AL ;
BANDITELLI, G ;
CINELLU, MA ;
SANNA, G ;
MINGHETTI, G ;
DEMARTIN, F ;
MANASSERO, M .
INORGANIC CHEMISTRY, 1989, 28 (03) :404-410
[3]   BIS-MU-[BIS(DIPHENYLPHOSPHINO)METHANE]-BIS(HALOGENOPLATINUM)(PT-PT) - DIMERIC COMPLEXES OF PLATINUM(I) CONTAINING A PLATINUM-PLATINUM BOND [J].
BROWN, MP ;
PUDDEPHATT, RJ ;
RASHIDI, M ;
SEDDON, KR .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (09) :951-955
[4]   DIPALLADIUM AND DIPLATINUM BIS(MU-ALKANETHIOLATO) COMPLEXES WITH A PLANAR M2S2 RING [J].
CAPDEVILA, M ;
CLEGG, W ;
GONZALEZDUARTE, P ;
HARRIS, B ;
MIRA, I ;
SOLA, J ;
TAYLOR, IC .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (19) :2817-2826
[5]   FASTER DATA-COLLECTION WITHOUT LOSS OF PRECISION - AN EXTENSION OF THE LEARNT PROFILE METHOD [J].
CLEGG, W .
ACTA CRYSTALLOGRAPHICA SECTION A, 1981, 37 (JAN) :22-28
[6]   THE STRUCTURAL CHEMISTRY OF METAL THIOLATE COMPLEXES [J].
DANCE, IG .
POLYHEDRON, 1986, 5 (05) :1037-1104
[7]   POLYNUCLEAR THIOLATE COMPLEXES IN SOLUTION - SOLUTION EQUILIBRIA STUDIES OF SILVER(I) COMPLEXES OF 3-(DIMETHYLAMINO)PROPANE-1-THIOL AND 3-AMINOPROPANE-1-THIOL AND COMPARATIVE-STUDY WITH 4-MERCAPTO-1-METHYLPIPERIDINE [J].
GONZALEZDUARTE, P ;
VIVES, J .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (08) :2483-2489
[8]  
HARRISON PM, 1985, METALLOPROTEINS 2
[9]  
HARRISON PM, 1985, METALLOPROTEINS 1
[10]   SOME NEW MONOHYDRIDOMONOPHOSPHIDO BRIDGED DIPLATINUM COMPLEXES [J].
JANS, J ;
NAEGELI, R ;
VENANZI, LM ;
ALBINATI, A .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 247 (02) :C37-C41