SUCCESSFUL X-RAY STRUCTURE-ANALYSIS OF AN ALKYLIDENE CARBENOID - A MILESTONE IN CARBENOID RESEARCH

被引：31

作者：

MAERCKER, A

机构：

[1] Institut Für Organische Chemie, Universität Siegen, D-57068, Adolf-Reichwein Strasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 07期

关键词：

D O I：

10.1002/anie.199310231

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As temporary climax in carbenoid research, G. Boche et al. (see p.1032 ff) succeeded in performing an X‐ray crystal analysis on 1‐chloro‐2,2‐bis(chlorophenyl)‐1‐lithioethene (1). The structure confirms that the carbenoid C atom has rehybridized, as predicted by Köbrich. This result will certainly give impetus to investigations into the relationship between structure and reactivity in carbenoids. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

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页码：1023 / 1025

页数：3

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