GEOMETRY OF MYRTENAL . A DETAILED ANALYSIS OF NUCLEAR MAGNETIC RESONANCE SPECTRUM OF A BICYCLO=3.1.1'HEPTENE-2 SYSTEM

被引:39
作者
KAPLAN, F
SCHULZ, CO
WEISLEDE.D
KLOPFENS.C
机构
[1] Department of Chemistry, University of Cincinnati, Cincinnati
关键词
D O I
10.1021/jo01269a005
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Detailed analyses of nuclear magnetic resonance spectra of myrtenal (I) are reported. The magnitude of spin-spin coupling through two, three, and four bonds is used to define the geometry of the system and is discussed, in part, in terms of bridged cyclobutanes. A large four-bond coupling (5.78 cps) is found between bridgehead protons. © 1968, American Chemical Society. All rights reserved.
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页码:1728 / &
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