INFRARED STUDY OF CARBON MONOXIDE OXYGEN AND CARBON DIOXIDE ADSORPTION ON CHROMIA-SILICA .3. CARBON MONOXIDE-OXYGEN INTERACTION

被引：10

作者：

ZECCHINA, A

GHIOTTI, G

MORTERRA, C

BORELLO, E

机构：

[1] Istituto di Chimica-Fisica, Università di Torino, Torino

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 05期

关键词：

D O I：

10.1021/j100725a021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The interaction between carbon monoxide and oxygen at room temperature on a chromia-silica catalyst has been studied by infrared spectroscopy. Only the adsorbed CO which causes the band at 2187 cm-1 actively participates in the oxidation reaction, thus acting as an intermediate of great activity. Oxygenated species, mainly of the carboxylate type, have also been detected in the 1800-1300-cm-1 frequency range.

引用

页码：1295 / &