The core potential of intermolecular forces applied to solubility of gases in liquids

被引:11
作者
Kihara, T. [1 ]
Jhon, M. S. [2 ,3 ]
机构
[1] Univ Tokyo, Fac Sci, Dept Phys, Tokyo 113, Japan
[2] Dong Guk Univ, Seoul, South Korea
[3] Korea Inst Sci & Technol, Seoul, South Korea
关键词
D O I
10.1016/0009-2614(70)87002-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A formula for the solubility of gases in nonpolar liquids is obtained on the basis of Kihara's core potential of intermolecular forces, which considers the size and shape of molecules. The formula contains two empirical parameters independent of the solute. The solubilities of Ne, Ar, Kr, Xe, N-2, CO2, C2H6, and cyclopropane in cyclohexane are well represented.
引用
收藏
页码:559 / 562
页数:4
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