ELECTRON-TRANSFER REACTIONS IN COFACIAL DIPORPHYRINS

被引：70

作者：

NETZEL, TL ^{[1
]}

KROGER, P ^{[1
]}

CHANG, CK ^{[1
]}

FUJITA, I ^{[1
]}

FAJER, J ^{[1
]}

机构：

[1] BROOKHAVEN NATL LAB,DEPT ENERGY & ENVIRONM,UPTON,NY 11973

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 67卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(79)85151-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Optical difference spectra consonant with electron transfer from a magnesium porphyrin to a free base porphyrin are obtained following picosecond excitation of cofacial diporphyrins covalently linked approximately 4 Å apart. The charge-transfer species decays with a lifetime of 620 ± 20 ps. © 1979.

引用

页码：223 / 228

页数：6

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