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SEP-LIF STUDY ON DYNAMICS OF VIBRATIONALLY EXCITED-STATES OF VANDERWAALS COMPLEXES - THE ANISOLE.AR COMPLEX

被引：9
作者：
TAKAYANAGI, M
HANAZAKI, I
机构：
[1] Institute for Molecular Science, Okazaki, 444, Myodaiji
来源：
CHEMICAL PHYSICS LETTERS | 1992年 / 190卷 / 1-2期
关键词：
D O I：
10.1016/0009-2614(92)86112-U
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two broad bands were found in the LIF spectrum of the anisole.Ar complex upon excitation by stimulated emission pumping to its 782 cm-1 vibrational state. This is the first example of the direct spectroscopic observation of species formed by vibrational relaxation or predissociation in the ground electronic state of van der Waals complexes containing large organic molecules. The vibrational dynamics was found to be complete within 300 ns after the excitation.
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页码：115 / 118
页数：4
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