GAS-PHASE REACTIONS INVOLVING HOT O-18(3P) ATOMS AND FORMALDEHYDE

被引：6

作者：

FERRIERI, RA

WOLF, AP

机构：

[1] Department of Chemistry, Brookhaven National Laboratory, Upton

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 18期

关键词：

D O I：

10.1021/j100197a007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report an investigation of the low-pressure gas-phase reactions involving hot (O(3P))-O-18 atoms with translational energies in excess of 1 eV and formaldehyde. Using mass spectrometry, O-18 incorporation in (COO)-O-16-O-18 and (HCO)-O-18 products was observed. These results strongly suggested that carbonyl bond addition was an important reaction at these energies.

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页码：7164 / 7166

页数：3

相关论文

共 23 条

[1]

Benson S.W., 1976, THERMOCHEMICAL KINET

[2] REACTION OF OXYGEN-ATOMS WITH ETHYLENE AND VINYL BROMIDE [J].

BUSS, RJ ;

BASEMAN, RJ ;

HE, G ;

LEE, YT .

JOURNAL OF PHOTOCHEMISTRY, 1981, 17 (3-4) :389-396

[3] REACTION-RATE AND PRODUCTS FOR THE REACTION O(P-3) + H2CO [J].

CHANG, JS ;

BARKER, JR .

JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (24) :3059-3064

[4] REACTION OF OXYGEN ATOMS WITH ACETALDEHYDE [J].

CVETANOVIC, RJ .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1956, 34 (06) :775-784

[5] HYDROGEN-ATOM MIGRATION IN THE OXIDATION OF ALDEHYDES - O(3P)+H2CO [J].

DUPUIS, M ;

LESTER, WA .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (09) :4193-4195

[6] REACTIONS INVOLVING HOT O(3P) ATOMS AND ISOMERIC 2-BUTENE [J].

FERRIERI, RA ;

WOLF, AP .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (12) :4747-4752

[7] ION SPUTTERING ON METAL-OXIDES - A SOURCE OF TRANSLATIONALLY HOT O(3PJ) ATOMS FOR CHEMICAL STUDIES ABOVE 1 EV [J].

FERRIERI, RA ;

CHU, YY .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1988, 59 (10) :2177-2184

[8]

FERRIERI RA, 1986, JPL PUBLICATION, V874, P119

[9]

FERRIERI RA, 1988, 13TH INT HOT AT CHEM, V43, P95

[10] ENERGY-DISTRIBUTIONS OF ATOMS SPUTTERED FROM POLYCRYSTALLINE SURFACES [J].

GARRISON, BJ .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1986, 17 (04) :305-308