INTERCALATION OF FLUOROMETALLATE ANIONS OF GROUP-VI METALS AND URANIUM IN GRAPHITE

被引：2

作者：

HAGIWARA, R ^{[1
]}

FUKUI, T ^{[1
]}

EMA, K ^{[1
]}

ITO, Y ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT NUCL ENGN,SAKYO KU,KYOTO 606,JAPAN

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 72卷 / 01期

关键词：

X-RAY DIFFRACTION; INTERCALATION; GROUP VI METALS; URANIUM; GRAPHITE; FORMATION ENTHALPY;

D O I：

10.1016/0022-1139(94)03170-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Systematic investigations have been made of the formation of graphite fluorometallates of the Group VI transition metals (molybdenum and tungsten) and uranium. The reactions were performed by interacting liquid or gaseous metal hexafluorides in the presence or absence of elemental fluorine at ambient temperature. The degree of intercalation of these metal fluorides depends on the formation enthalpy of the fluorometallate anion from the original metal hexafluoride, as has been found for other intercalation reactions of binary fluorides.

引用

页码：23 / 28

页数：6

共 24 条

[1]

Bartlett, Okino, Mallouk, Hagiwara, Lerner, Rosenthal, Kourtakis, Adv. Chem. Ser. No. 226, Electron Transfer in Biology and the Solid State: Inorganic Compounds with Unusual Properties, (1990)

[2]

Lerner, Hagiwara, Bartlett, J. Fluorine Chem., 57, (1992)

[3]

Annis, Datz, J. Chem., Phys., 66, (1977)

[4]

George, Beauchamp, Chem. Phys., 36, (1979)

[5]

Beauchamp, J. Chem. Phys., 64, (1976)

[6]

Hamwi, Touzain, Bonnetain, Mater. Sci. Eng., 31, (1977)

[7]

Bartlett, McCarron, McQuillan, Thompson, Novel graphite salts and their electrical conductivities, Synthetic Metals, 1, (1979)

[8]

Vaknin, Davidov, Selig, On the role of inorganic fluorine chemistry in the study of synthetic metals, Journal of Fluorine Chemistry, 32, (1986)

[9]

Nakajima, Molinier, Synth. Metals, 34, (1989)

[10]

Opalovskii, Kuznetsova, Chicagov, Nazarov, Uminskii, russ. J. Inorg. Chem., 19, (1974)

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