MATRIX SPECTROSCOPY OF 2-ADAMANTYLIDENE, A DIALKYLCARBENE WITH SINGLET GROUND-STATE

被引：39

作者：

BALLY, T

MATZINGER, S

TRUTTMANN, L

PLATZ, MS

MORGAN, S

机构：

[1] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210

[2] DANA COLL,DEPT CHEM,BLAIR,NE 68008

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 19期

关键词：

D O I：

10.1002/anie.199419641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A broad band at λmax ≈ 620 mm confirms the singlet character of the carbene 1, since no other conceivable compounds in the system should absorb in this region. Moreover, calculations on dialkylcarbenes yield similar λ values. Compound 1 rearranges photochemically to 2, and on warming in a CO‐doped argon matrix it affords 3. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1964 / 1966

页数：3

共 24 条

[1]

ADDING AC, 1966, J CHEM SOC CHEM COMM, P657

[2] DICYCLOPROPYLCARBENE - DIRECT CHARACTERIZATION OF A SINGLET DIALKYLCARBENE [J].