SYNTHESIS AND X-RAY STRUCTURE-ANALYSIS OF A MO COMPLEX WITH ETA-2-COORDINATED BENZALDEHYDE - TRANSFORMATION OF A CO LIGAND BY DOUBLE ALPHA-ADDITION

被引：32

作者：

BRUNNER, H ^{[1
]}

WACHTER, J ^{[1
]}

BERNAL, I ^{[1
]}

CRESWICK, M ^{[1
]}

机构：

[1] UNIV HOUSTON,DEPT CHEM,HOUSTON,TX 77044

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 11期

关键词：

D O I：

10.1002/anie.197908611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molybdenum serves as spiro‐atom in the complex 3 formed from 1, R  CH3, and PhMgBr in the molar ratio of 1:2. One of the two CO groups is transformed into C,O‐coordinated benzaldehyde. Ring contraction (1) → (2) is already known. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

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页码：861 / 862

页数：2

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