GROWTH OF FINE PARTICLES OF THE FE-N SYSTEM PREPARED BY REACTIVE GAS EVAPORATION TECHNIQUE

被引:12
作者
YAMAUCHI, K
YATSUYA, S
MIHAMA, K
机构
[1] Department of Applied Physics, Faculty of Engineering, Nagoya University, Nagoya
关键词
D O I
10.1016/0022-0248(79)90177-5
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Evaporation of iron at a reduced pressure varying from a few to 200 Torr of ammonia causes the growth of several kinds of fine particles of the Fe-N system. The particles thus prepared were studied by means of electron microscopy. At a few Torr of gas pressure, particles of α-Fe (bcc) and γ-Fe (fcc) show the truncated rhombic dodecahedron and mainly needle habits, respectively. The former is characteristic of bcc metals while the latter is a modification of the well-known pentagonal decahedron of multiply twinned particles. The lattice parameter of the γ-Fe is 3.64 ± 0.03 Å, which corresponds to the nitrogen content of 2.5 wt%. Above 100 Torr of gas pressure, particles of γ′-Fe4N grow. The particles collected on carbon films in the inner and outer zones are sometimes aggregated in clusters. © 1979.
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页码:615 / 619
页数:5
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