ANODIC-OXIDATION OF METHYLBENZENES - SYNTHETIC ROUTES TO CERTAIN CYCLOHEXA-1,4-DIENES

被引：6

作者：

BARBA, I

CHINCHILLA, R

GOMEZ, C

机构：

[1] Departamento de Quimica Orgánica, Universidad de Alicante, 03080-Alicante

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 11期

关键词：

D O I：

10.1021/jo00011a042

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The anodic methoxylation of a series of methylbenzenes (mesitylene, pseudocumene, hemimellitene, pentamethylbenzene, and hexamethylbenzene) afforded chain methoxylated products as well as nuclear-addition products. For nuclear-addition products both cis/trans isomers are possible. In the cyclohexa-1,4-dienes obtained from these substrates the cis/trans ratio found is different. A probable mechanism is provided.

引用

页码：3673 / 3676

页数：4

共 21 条

[1]

ALONSO F, 1990, TETRAHEDRON, V46, P2096

[2]

BARBA F, 1986, J CHEM RES-S, P228

[3] ELECTROCHEMICAL OBTENTION OF CIS-3,6-DIMETHOXY-3,6-DIMETHYL-1,4-CYCLOHEXADIENE AND TRANS-3,6-DIMETHOXY-3,6-DIMETHYL-1,4-CYCLOHEXADIENE [J].