AQUEOUS DISPERSIONS OF ELECTRICALLY CONDUCTING MONODISPERSE POLYPYRROLE PARTICLES

被引：157

作者：

ARMES, SP ^{[1
]}

MILLER, JF ^{[1
]}

VINCENT, B ^{[1
]}

机构：

[1] UNIV BRISTOL,DEPT PHYS CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1987年 / 118卷 / 02期

关键词：

POLYMERS - Electric Conductivity;

D O I：

10.1016/0021-9797(87)90476-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Stable, aqueous dispersions of polypyrrole latex particles were prepared by a dispersion polymerization technique using ferric chloride as the initiator and primarily hydrolyzed poly(vinyl acetate) as the stabilizer. Monodisperse particles in the approximate size range from 100 to 150 nm diameter were obtained. At the optimum PVA:pyrrole mass ratio (corresponding to the 'knee' in the PVA adsorption isotherm on polypyrrole particles), the electrical conductivity of the particles is approximately 5 OMEGA ** minus **1 cm** minus **1.

引用

页码：410 / 416

页数：7

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