AN EXPLICIT CLUSTER MODEL FOR BINARY NUCLEI IN WATER ALCOHOL SYSTEMS

被引：50

作者：

LAAKSONEN, A

KULMALA, M

机构：

[1] University of Helsinki, Department of Physics, SF-00170 Helsinki

来源：

JOURNAL OF CHEMICAL PHYSICS | 1991年 / 95卷 / 09期

关键词：

D O I：

10.1063/1.461513

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new thermodynamical model for the description of critical clusters in water-alcohol systems has been developed. The clusters are divided into an interior layer and a unimolecular surface layer. The surface excess of alcohol in the cluster is the same as in macroscopic liquid. The model is applied to binary nucleation of water and ethanol. The predictions of the model agree fairly well with experimental results.

引用

页码：6745 / 6748

页数：4

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[2]

Becker R, 1935, ANN PHYS-BERLIN, V24, P719

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