CRYSTAL-STRUCTURE OF AMMONIUM TRIMOLYBDATE MONOHYDRATE (NH4)(2)MO3O10-CENTER-DOT-H2O BY POWDER DIFFRACTION METHOD

被引：12

作者：

LASOCHA, W ^{[1
]}

JANSEN, J ^{[1
]}

SCHENK, H ^{[1
]}

机构：

[1] UNIV AMSTERDAM,CRYSTALLOG LAB,1018 WV AMSTERDAM,NETHERLANDS

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1995年 / 116卷 / 02期

关键词：

D O I：

10.1006/jssc.1995.1235

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of the fibrillar ammonium trimolybdate monohydrate (NH4)(2)Mo3O10 . H2O was solved by the Direct Method and Powder Diffraction package POWSIM, and refined by the Rietveld method to R(F) = 6.4 and R(wp) = 17.1%. Distorted edge-shared MoO6 octahedra (Mo-O = 1.71-2.62) form infinite chains, built up of Mo3O10 units, parallel to the [010] axis. The space group is P2(1)/m (11), with lattice parameters a = 9.638(1), b = 7.577(2), c = 8.537(1) Angstrom, beta = 112.89(1)degrees, V = 574.4(2) Angstrom(3), Z = 2. (C) 1995 Academic Press, Inc.

引用

页码：422 / 426

页数：5

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