DENSITY DEPENDENCE OF EXPERIMENTAL TRANSPORT COEFFICIENTS OF GASES

被引:54
作者
HANLEY, HJM
MCCARTY, RD
SENGERS, JV
机构
[1] Cryogenics Division, Institute for Basic Standards, National Bureau of Standards, Boulder
[2] Institute for Molecular Physics, University of Maryland, College Park
关键词
D O I
10.1063/1.1671137
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We analyze experimental transport data for several gases as a function of density and temperature. Necessary conditions are proposed to check if the data are consistent with a given density function at fixed temperature. It is found that the theoretically suggested density function, which involves terms logarithmic in the density, satisfies the conditions for the data examined in the temperature and pressure ranges considered. Based on the analyses, first density coefficients of thermal conductivity and viscosity are reported, together with an assessment of their precision, at reduced temperatures up to T*≈30.
引用
收藏
页码:857 / &
相关论文
共 47 条
[1]   VISCOSITY OF HYDROGEN DEUTERIUM METHANE + CARBON MONOXIDE FROM MINUS 50 DEGREE TO 150 DEGREE C BELOW 200 ATMOSPHERES [J].
BARUA, AK ;
ROSS, J ;
AFZAL, M ;
FLYNN, GP .
JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (02) :374-&
[2]   ON PRINCIPLE OF CORRESPONDING STATES FOR VISCOSITY OF SIMPLE LIQUIDS [J].
BOON, JP ;
LEGROS, JC ;
THOMAES, G .
PHYSICA, 1967, 33 (03) :547-&
[3]  
BOULDER, 1967, LECTURES THEORETIC C, V9
[4]  
BRITTIN WE, 1967, LECTURES THEORE C ED, V9
[5]  
BRITTIN WE, 1967, LECTURES THEORE C ED, V9, P335
[6]  
Chapman S., 1939, MATHEMATICAL THEORY, pchapt 16
[7]  
CURTISS CF, 1965, INT J ENG SCI, V3, P269
[8]   ON DENSITY EXPANSION OF PAIR DISTRIBUTION FUNCTION FOR A DENSE GAS NOT IN EQUILIBRIUM [J].
DORFMAN, JR ;
COHEN, EGD .
PHYSICS LETTERS, 1965, 16 (02) :124-&
[9]   DIFFICULTIES IN KINETIC THEORY OF DENSE GASES [J].
DORFMAN, JR ;
COHEN, EGD .
JOURNAL OF MATHEMATICAL PHYSICS, 1967, 8 (02) :282-&
[10]   LOGARITHMIC DENSITY BEHAVIOR OF A NONEQUILIBRIUM BOLTZMANN GAS [J].
GOLDMAN, R ;
FRIEMAN, EA .
JOURNAL OF MATHEMATICAL PHYSICS, 1967, 8 (07) :1410-&