VOLATILITY STUDIES OF METAL-CHELATES .4. THERMAL-BEHAVIOR OF COPPER(II) CHELATES OF ARYL BETA-DIKETONES

被引：11

作者：

DILLI, S

ROBARDS, K

机构：

[1] School of Chemistry, University of New South Wales, Kensington, NSW, 2033

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1979年 / 32卷 / 02期

关键词：

D O I：

10.1071/CH9790277

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thermal stability and volatility of the copper(II) chelates of 38 aryl β-diketones have been examined by combined thermogravimetry and differential thermal analysis. Volatility is characterized by fluorine substitution (in R and R' of RCOCH2COR'), particularly in the alkyl (R) moiety of the β-diketone. When chlorine, bromine and methyl substituents are introduced into the aromatic ring (R'), there is a significant reduction in volatility. If R is CH3, thermal stability is markedly affected, especially when R' is C6F5. © 1979, CSIRO. All rights reserved.

引用

页码：277 / 284

页数：8

共 17 条

[1]

[Anonymous], 1969, ORGANIC FLUORINE CHE

[2] A STUDY OF THE VOLATILE CHARACTERISTICS OF VARIOUS METAL BETA-DIKETONE CHELATES [J].