A new double minimum problem: The B-1 Sigma(+) state of BH

被引：19

作者：

Browne, J. C. ^{[1
]}

Greenawalt, E. M. ^{[2
]}

机构：

[1] Univ Texas Austin, Dept Comp Sci & Phys, Austin, TX 78712 USA

[2] Univ Texas Austin, Dept Comp Sci, Austin, TX 78712 USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 7卷 / 03期

关键词：

D O I：

10.1016/0009-2614(70)80184-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An extended configuration interaction calculation of the wavefunction and potential curve for the B-1 Sigma(+) state of BH reveals that this state has a double minimum in its potential curve somewhat analogous to the E, F-1 Sigma(+)(g) state of H-2. Only the transitions to levels in the inner minimum have yet been observed spectroscopically. K Predictions are made of the position and spacings of vibrational levels in the outer minimum and above the maximum in the B-1 Sigma(+) potential curve.

引用

页码：363 / 367

页数：5

共 7 条

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[3] MODIFIED ATOMS-IN-MOLECULES MODEL FOR PREDICTING DIATOMIC GROUND-AND EXCITED-STATE POTENTIAL-ENERGY CURVES .1. LIH,BEH,AND BH
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[6] RYDBERG STATES OF MOLECULES .I.-.V.
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[7] MULLIKEN RS, 1964, PHYS REV, V136, pA862

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