DIISOPROPYL TARTRATE MODIFIED (E)-GAMMA-[(CYCLOHEXYLOXY)DIMETHYLSILYL]-ALLYLBORONATE, A CHIRAL REAGENT FOR THE STEREOSELECTIVE SYNTHESIS OF ANTI 1,2-DIOLS VIA THE FORMAL ALPHA-HYDROXYALLYLATION OF ALDEHYDES

被引：36

作者：

ROUSH, WR

GROVER, PT

LIN, XF

机构：

[1] Department of Chemistry Indiana University, Bloomington

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(00)97299-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An enantioselective synthesis of anti 1,2-diols via the reactions of aldehydes and the tartrate ester modified gamma-(alkoxysilyl)allylboronate 2 has been developed. This method is most effective in double asymmetric reactions with chiral aldehydes.

引用

页码：7563 / 7566

页数：4

共 39 条

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