INTERCALATION CHEMISTRY OF CONDUCTING POLYMERS - NEW CRYSTALLINE MICROLAMINATE PHASES IN THE POLYANILINE FEOCL SYSTEM

被引：96

作者：

KANATZIDIS, MG

WU, CG

MARCY, HO

DEGROOT, DC

KANNEWURF, CR

KOSTIKAS, A

机构：

[1] Department of Chemistry, Center for Fundamental Materials Research, Michigan State University, East Lansing, Michigan

[2] Department of Electrical Engineering, Computer Science Northwestern University, Evanston, Illinois

[3] Nuclear Research Center Demokritos, Attiki, Aghia Paraskevi

来源：

ADVANCED MATERIALS | 1990年 / 2卷 / 08期

关键词：

D O I：

10.1002/adma.19900020806

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular nano‐composites of two electrically active but chemically deverse components, organic conducting polymers and inorganic metaloxide bronzes, can be formed by the in situ intercalative oxidative polymerization of aniline in FeOCl. Two forms of the normally amorphous polyaniline, in a cryustalline, well‐defined environment have been discovered, one semiconducting and one metallic. These hybrid materials are also suitable for the study of oriented conducting polymers. Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：364 / 366

页数：3

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