A COMPARISON OF BLOCK COPOLYMER SURFACTANT GELS

被引:58
作者
SCHMOLKA, IR
机构
[1] Irving R. Schmolka Co., Grosse He, 48138, MI
关键词
GELS; MICELLES; POLOXAMERS; REVERSIBLE GELATION; SPRAY GELS;
D O I
10.1007/BF02657771
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The aqueous gel forming properties of three series of block copolymer surfactants, poloxamers, poloxamines, and Butronic(R) polyols, are briefly reviewed and compared. The differences in their gel formation properties are explained. Aqueous gel formation of these polymers is attributed to the aggregation of extended linear coil micelles in which the hydrophilic ends become entangled as the temperature rises, due to dehydration. The failure of the Butronic polyol gels to exhibit the same reverse thermal behavior shown by the other two polyol series is attributed to a more lipophilic hydrophobe and to the larger number of moles of water associated with the Butronic hydrophile. The reverse thermal characteristics of aqueous poloxamer and poloxamine solutions has led to the development of aerosol detergent systems which can form foamy gels, thereby expanding the usefulness of these surfactants.
引用
收藏
页码:206 / 209
页数:4
相关论文
共 29 条
[1]  
ADAMS DV, 1985, Patent No. 4534958
[2]  
ANDERSON RA, 1972, PHARM ACTA HELV, V47, P304
[3]  
ATTWOOD D, 1983, Journal of Pharmacy and Pharmacology, V35, p54P
[4]  
BECHER P, 1959, J PHYS CHEM-US, V63, P1615
[6]  
CHENCHOW PC, 1979, THESIS OHIO STATE U
[7]   ULTRACENTRIFUGAL DETERMINATION OF THE MICELLAR CHARACTER OF NON-IONIC DETERGENT SOLUTIONS [J].
DWIGGINS, CW ;
BOLEN, RJ ;
DUNNING, HN .
JOURNAL OF PHYSICAL CHEMISTRY, 1960, 64 (09) :1175-1178
[8]   NUCLEAR MAGNETIC-RESONANCE STUDIES OF INTERACTIONS BETWEEN OXYETHYLENE-OXYPROPYLENE POLYMER, MACROGOL AND PHENOL [J].
JACOBS, J ;
ANDERSON, RA ;
WATSON, TR .
JOURNAL OF PHARMACY AND PHARMACOLOGY, 1972, 24 (07) :586-&
[9]  
LUNDSTED LG, 1955, Patent No. 722746
[10]  
MANKOWICH AM, 1954, J PHYS CHEM-US, V58, P1028