SOLID C-60 - A NEW FORM OF CARBON

被引：6934

作者：

KRATSCHMER, W ^{[1
]}

LAMB, LD ^{[1
]}

FOSTIROPOULOS, K ^{[1
]}

HUFFMAN, DR ^{[1
]}

机构：

[1] UNIV ARIZONA,DEPT PHYS,TUCSON,AZ 85721

来源：

NATURE | 1990年 / 347卷 / 6291期

关键词：

D O I：

10.1038/347354a0

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

A new form of pure, solid carbon has been synthesized consisting of a somewhat disordered hexagonal close packing of soccer-ball-shaped C60 molecules. Infrared spectra and X-ray diffraction studies of the molecular packing confirm that the molecules have the anticipated 'fullerene' structure. Mass spectroscopy shows that the C70 molecule is present at levels of a few per cent. The solid-state and molecular properties of C60 and its possible role in interstellar space can now be studied in detail. © 1990 Nature Publishing Group.

引用

页码：354 / 358

页数：5

共 34 条

[1] POLYCYCLIC AROMATIC-HYDROCARBONS AND THE UNIDENTIFIED INFRARED-EMISSION BANDS - AUTO EXHAUST ALONG THE MILKY-WAY
ALLAMANDOLA, LJ
TIELENS, AGGM
BARKER, JR
[J]. ASTROPHYSICAL JOURNAL, 1985, 290 (01) : L25 - L28
[2] Imperfections in the structure of cobalt I. Experimental work and proposed structure
Edwards, OS
Lipson, H
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1942, 180 (A982) : 0268 - 0277
[3] Structure of cobalt
Edwards, OS
Lipson, H
Wilson, AJC
[J]. NATURE, 1941, 148 : 165 - 165
[4] ICOSAHEDRAL C-60 - AN AROMATIC MOLECULE WITH A VANISHINGLY SMALL RING CURRENT MAGNETIC-SUSCEPTIBILITY
ELSER, V
HADDON, RC
[J]. NATURE, 1987, 325 (6107) : 792 - 794
[5] ELECTRIC AND MAGNETIC-PROPERTIES OF THE AROMATIC 60-CARBON CAGE
FOWLER, PW
LAZZERETTI, P
ZANASI, R
[J]. CHEMICAL PHYSICS LETTERS, 1990, 165 (01) : 79 - 86
[6] ELECTRONIC-STRUCTURE AND BONDING IN ICOSAHEDRAL C-60
HADDON, RC
BRUS, LE
RAGHAVACHARI, K
[J]. CHEMICAL PHYSICS LETTERS, 1986, 125 (5-6) : 459 - 464
[7] ICOSAHEDRAL C-60 REVISITED - AN AROMATIC MOLECULE WITH A VANISHINGLY SMALL RING CURRENT MAGNETIC-SUSCEPTIBILITY - COMMENT
HADDON, RC
ELSER, V
[J]. CHEMICAL PHYSICS LETTERS, 1990, 169 (04) : 362 - 364
[8] THE UV ABSORPTION-SPECTRUM OF C-60 (BUCKMINSTERFULLERENE) - A NARROW-BAND AT 3860-A
HEATH, JR
CURL, RF
SMALLEY, RE
[J]. JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (07) : 4236 - 4238
[9] Hendricks SB, 1930, Z KRISTALLOGR, V73, P376
[10] DIFFUSE INTERSTELLAR BANDS .4. REGION 4400-6850 A
HERBIG, GH
[J]. ASTROPHYSICAL JOURNAL, 1975, 196 (01) : 129 - &

← 1 2 3 4 →