CATALYTIC ACTIVITY OF METAL-CARBONYL CLUSTER COMPOUNDS - HYDROFORMYLATION AND HYDROESTERIFICATION CATALYZED BY CO4(CO)12 AND CO2(CO)8

被引：18

作者：

LENNERTZ, AM

LAEGE, J

MIRBACH, MJ

SAUS, A

机构：

[1] INST TECH CHEM & PETROLCHEM,ALTE MAASTRICHTER STR 2,D-5100 AACHEN,FED REP GER

[2] UNIV DUISBURG,FACHBEREICH ANGEW CHEM 6,D-4100 DUISBURG,FED REP GER

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 171卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)81541-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The carbonyl complexes Co2(CO)8 and Co4(CO)12 catalyze the hydroformylation and hydroesterification reactions via the same catalytic cycle. The entry into this cycle via HCo(CO)3 is easier with Co4(CO)12 than with Co2(CO)8, and so the former is the more active catalyst. © 1979.

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页码：203 / 207

页数：5

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