THE TETRAMERIC ALUMINUM(I) COMPOUND [(AL(ETA-5-C5ME5))4]

被引：320

作者：

DOHMEIER, C

ROBL, C

TACKE, M

SCHNOCKEL, H

机构：

[1] Institut für Anorganische Chemie der Universität, München, W-8000

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 05期

关键词：

D O I：

10.1002/anie.199105641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetrameric, eta-5-coordinated aluminum(I) compound \{Al(C5Me5)}4\ (1) is stable at room temperature. It was prepared from AlCl and [Mg(C5Me5)2]. In this cluster, four Al atoms form a regular tetrahedron and the planes of the C5Me5 rings lie nearly parallel to the respective faces of the tetrahedron.

引用

页码：564 / 565

页数：2

共 19 条

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