REDUCTION OF AROMATIC NITRO-COMPOUNDS TO AMINES WITH SODIUM BOROHYDRIDE COPPER(II) ACETYLACETONATE

被引：65

作者：

HANAYA, K ^{[1
]}

MURAMATSU, T ^{[1
]}

KUDO, H ^{[1
]}

CHOW, YL ^{[1
]}

机构：

[1] SIMON FRASER UNIV,DEPT CHEM,BURNABY V5A 1S6,BC,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 10期

关键词：

D O I：

10.1039/p19790002409

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reduction of aromatic nitro-compounds by NaBH4 in ethanol in the presence of various transition metal acetylacetonates has been investigated. Copper(II) acetylacetonate was found to be the most effective catalyst for reduction to the corresponding amines. This reaction appears to proceed through a hydride metal complex.

引用

页码：2409 / 2410

页数：2

共 8 条

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