C-H ACTIVATION OF PHENYLACETYLENE BY THE CYCLOMETALATED PLATINUM(II) COMPLEX OF 1,1,2,2-TETRAACETYLETHANE - PREPARATION OF THE BIS(SIGMA-PHENYLACETYLIDE)PLATINUM(II) COMPLEX

被引：11

作者：

YAMAZAKI, S

机构：

[1] Chemistry Laboratory, Kochi Gakuen College, Kochi, 780

来源：

POLYHEDRON | 1992年 / 11卷 / 16期

关键词：

D O I：

10.1016/S0277-5387(00)83152-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cyclometallated platinum(II) complex of 1,1,2,2-tetraacetylethane (dahd2- = 3,4-diacetyl-2,4-hexadiene-2,5-diolate dianion). [Pt(dahd-C3, O')(L2)] [L = PMe2Ph; L2 = 1,2-bis(diphenylphosphino)ethane (bdpe)], reacts with the monosubstituted acetylene, phenyl acetylene, activating its C-H bond to afford a new bis(sigma-alkynyl) platinum(II) complex (L = PMe2Ph, trans form; L2 = bdpe, cis form) in good yield.

引用

页码：1983 / 1985

页数：3

共 16 条

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