OXIDATION MECHANISMS ON ALPHA-BRASSES (10 AND 30 AT-PERCENT-ZN) BY OPTICAL METHODS AND SIMS

被引：5

作者：

BEUCHER, E ^{[1
]}

LENGLET, M ^{[1
]}

WEBER, S ^{[1
]}

SCHERRER, S ^{[1
]}

机构：

[1] ECOLE MINES NANCY,PHYS SOLIDE LAB,F-54000 NANCY,FRANCE

来源：

SURFACE AND INTERFACE ANALYSIS | 1992年 / 18卷 / 09期

关键词：

D O I：

10.1002/sia.740180907

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Optical methods-Fourier transform infrared spectroscopy, ultraviolet-visible-near-infrared spectroscopy (UV-Vis-NIR)-are used to control the oxidation products grown on the surface of cold-worked alpha-brasses (10 and 30 at.% zinc). The influence of sample preparation (mechanical polishing and chemical cleanings) on oxidation rates is also studied. The duplex oxide scale (copper oxides on the top of the layer and zinc oxide at the metal/oxide interface) obtained during brass oxidation and perfectly exhibited by SIMS depth profiles can be explained in terms of internal oxidation and of the semiconductor properties of ZnO and Cu2O.

引用

页码：673 / 678

页数：6

共 11 条

[1]

BEUCHER E, 1990, ANALUSIS, V18, P547

[2] OPTICAL-PROPERTIES OF MICROCRYSTALLINE ZINC-OXIDE - INFLUENCE OF DEFECTS PRODUCED BY INTERACTION WITH CARBON-MONOXIDE [J].

BOCCUZZI, F ;

GHIOTTI, G ;

CHIORINO, A .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1983, 79 :1779-1789

[3]

Dunn JS, 1931, J I MET, V46, P25

[4] INITIAL-STAGE OF COPPER THERMAL-OXIDATION STUDIED BY UV-VIS-NIR REFLECTANCE SPECTROSCOPY, XPS AND X-RAY-DIFFRACTION [J].

MACHEFERT, JM ;

DHUYSSER, A ;

LENGLET, M ;

LOPITAUX, J ;

DELAHAYE, D .

MATERIALS RESEARCH BULLETIN, 1988, 23 (10) :1379-1388

[5]

MAROIE S, 1982, THESIS U NOTRE DAME

[6]

RICHARDSON FD, 1948, J IRON STEEL I, V160, P261

[7]

RIVES A, UNPUB XPS RESULTS

[8]

SOUCHET R, 1991, ECASIA 91 BUDAPEST

[9] SURFACE COMPOSITION, OXIDATION AND SULFIDATION OF COLD-WORKED BRASS AND BRASS-COATED STEEL WIRE AS STUDIED BY X-RAY PHOTOELECTRON-SPECTROSCOPY .1. SURFACE COMPOSITION OF COMMERCIAL COLD-WORKED BRASS [J].

VANOOIJ, WJ .

SURFACE TECHNOLOGY, 1977, 6 (01) :1-18

[10] THEORETICAL ANALYSIS OF THE DIFFUSION PROCESSES DETERMINING THE OXIDATION RATE OF ALLOYS [J].

WAGNER, C .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1952, 99 (10) :369-380

← 1 2 →