CHEMICAL AND ELECTROCHEMICAL PREPARATION OF POLY(9,10-DIHYDROPHENANTHRENE-2,7-DIYL) USING NICKEL-COMPLEXES AND ELECTROCHEMICAL PROPERTIES OF THE POLYMER

被引：22

作者：

SAITO, N

KANBARA, T

SATO, T

YAMAMOTO, T

机构：

[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,4259 NAGATSUTA,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN

[2] GEN SEKIYU KK,CENT RES LAB,UKISHIMACHO,KAWASAKI 210,JAPAN

来源：

POLYMER BULLETIN | 1993年 / 30卷 / 03期

关键词：

D O I：

10.1007/BF00343062

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Dehalogenation polycondensations of 2,7-dibromo-9,10-dihydrophenanthrene with isolated zero-valent nickel complex and electrochemically generated zero-valent nickel complex afford pi-conjugated poly(9,10-dihydrophenanthrene-2,7-diyl). The electrochemically synthesized polymer is obtained as a thin film on electrode, and shows a reversible electrochemically doping-undoping cycle in an oxidation region. The polymer has essentially the same pi-conjugation system as that of poly(p-phenylene).

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页码：285 / 290

页数：6

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