PHOSPHOROTHIOATE AND PHOSPHORAMIDE ANALOGS OF DIHYDROXYACETONE PHOSPHATE

被引:15
作者
DUNCAN, R [1 ]
DRUECKHAMMER, DG [1 ]
机构
[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
关键词
D O I
10.1016/S0040-4039(00)60764-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The phosphorothioate analog of dihydroxyacetone phosphate has been prepared by reaction of bromohydroxyacetone with trisodium thiophosphate in aqueous solution. The enzymatic oxidation of 3-amino-1,2-propanediol phosphoramide with glycerol-3-phosphate oxidase has been demonstrated as a route to the corresponding phosphoramide analog.
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页码:1733 / 1736
页数:4
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