NONVANISHING COEFFICIENTS OF DIPOLE MOMENT EXPANSION IN AXIALLY SYMMETRIC MOLECULES

被引:9
作者
PAPOUSEK, D
SARKA, K
机构
[1] Institute of Physical Chemistry, Czechoslovak Academy of Sciences, Prague
[2] the Institute of Inorganic Chemistry, Slovak Academy of Sciences, Bratislava
关键词
D O I
10.1016/0022-2852(68)90002-7
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Schur's Lemma of the theory of groups has been used for the determination of the relations among the dipole moment expansion coefficients for the doubly degenerate coordinates in axially symmetric molecules. The role of the orientation of the degenerate coordinates is discussed. The relations between the non-vanishing second- and third-order coefficients of important point groups are summarized in tables. © 1968.
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页码:125 / &
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