ICOSAHEDRAL CARBORANES .12. DIRECT FLUORINATION OF O-,M-, AND RHO-CARBORANE

被引：30

作者：

KONGPRICHA, S

SCHROEDER, H

机构：

[1] Olin Research Center, Chemicals Group, New Haven

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 11期

关键词：

D O I：

10.1021/ic50081a040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the parent carboranes with excess elemental fluorine in liquid hydrogen fluoride resulted in o-, m-, and p-B10F10-C2H2 in yields of 30, 60, and 85%, respectively. Replacement of carbon-bonded hydrogen did not occur; however, perfluoro- m-carborane was obtained by direct fluorination of m-B10H10C2F2. All three B-decafluorocarboranes will hydrolyze either on immersion in water or exposure to moist air contrasting the hydrolytic stability of all other B-polyhalocarborane species. © 1969, American Chemical Society. All rights reserved.

引用

页码：2449 / +

页数：1

共 27 条

[1]

ADMAS R, 1963, INORG CHEM, V2, P1087

[2] HALOGENATION IN THE LIQUID PHASE BY MEANS OF CHLORINE TRIFLUORIDE [J].