THE EFFECT OF ALKANES ON THE FORMATION OF ULTRAFINE SILVER BROMIDE PARTICLES IN IONIC W/O MICROEMULSIONS

Ultrafine AgBr particles formed in w/o microemulsions with different chain length of alkanes were studied by UV-VIS spectrophotometry, stopped-flow spectrophotometry and transmission electron microscopy. The ultrafine particles of AgBr (5-7 nm in diameter) were obtained by mixing two separately prepared microemulsion systems both containing AOT, n-hexane and an aqueous solution of either AgNO3 or NaBr. The size distribution of the nearly spherical AgBr particles broadened from 5 to about 10 nm as chain length of alkane was increased from n-hexane to n-octane. When n-dodecane or a higher alkane was used, the microemulsion system became increasingly unstable causing precipitation of AgBr.