SIMULTANEOUS SPECIATION OF BUTYLTIN AND PHENYLTIN COMPOUNDS IN THE WATERS OF SOUTH-WEST SPAIN

被引:20
作者
GOMEZARIZA, JL
MORALES, E
RUIZBENITEZ, M
机构
[1] Department of Analytical Chemistry, Faculty of Chemistry, University of Seville, Seville
关键词
ORGANOTIN; TRIBUTYLTIN AND TRIPHENYLTIN; GAS CHROMATOGRAPHY FLAME PHOTOMETRIC DETECTION; SPECIATION; SPANISH WATERS; SOUTH-WEST SPAIN;
D O I
10.1039/an9921700641
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
An analytical method for the simultaneous speciation of butyltin and phenyltin compounds has been applied to a study of the water quality in six locations (rivers and sea) in South West Spain. It was not intended to provide a comprehensive survey of the area but to establish what the maximum levels might be for a subsequent and more detailed study. Phenyltin species were not found in any sample, however tributyltin was present (100-400 ng l-1) in the Cadiz Bay samples, which suggests that the biological water quality may sometimes be depressed. Wherever tributyltin was present, dibutyltin and monobutyltin occurred, possibly, as a result of a degradation process.
引用
收藏
页码:641 / 644
页数:4
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