LIQUID-STATE INTEGRAL-EQUATIONS AT HIGH-DENSITY - ON THE MATHEMATICAL ORIGIN OF INFINITE-RANGE OSCILLATORY SOLUTIONS

被引：43

作者：

HENDERSON, JR

SABEUR, ZA

机构：

[1] School of Chemistry, University of Leeds, Leeds

来源：

JOURNAL OF CHEMICAL PHYSICS | 1992年 / 97卷 / 09期

关键词：

D O I：

10.1063/1.463652

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Analytic asymptotic analysis and finite element numerical procedures are used to elucidate the mathematical reasons for the appearance of infinite-range oscillatory solutions to certain integral equation theories of wall-fluid interfacial structure and liquid state radial distribution functions. The results contribute to two issues of recent debate: (i) what physical significance (if any) can be attributed to the apparent "solidlike" structure that is often (but not always) seen in high density solutions to liquid state integral equation theories and (ii) is the same mathematical structure present in density functional theories (i.e., in the presence of a variational condition arising from a free energy functional)?

引用

页码：6750 / 6758

页数：9

共 23 条

[1] GENERALIZED VANDERWAALS THEORIES AND THE ASYMPTOTIC FORM OF THE DENSITY PROFILE OF A LIQUID VAPOR INTERFACE [J].