PREPARATION OF ALPHA,BETA-UNSATURATED METHYL KETONES FROM DIKETENE USING BIS(TRIBUTYLTIN) OXIDE

被引：13

作者：

SHIBATA, I

NISHIO, M

BABA, A

MATSUDA, H

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 07期

关键词：

D O I：

10.1246/cl.1993.1219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel type tin enolate is easily formed by the regioselective ring cleavage of diketene with Bis(tributyltin) oxide [(n-Bu3Sn)2O]. The enolate caused carbon-carbon bond formation with aldehydes. As a result, alpha,beta-unsaturated methyl ketones were obtained in good yields, accompanied by decarboxylation.

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页码：1219 / 1222

页数：4

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